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Sku SC15-8602_25_MG
US-Strem
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Product Information

Product Name
(3aR,8aR)-Tetrahydro-6-hydroxy-2,2-dimethyl-4,4,8,8-tetra-2-naphthalenyl-6-oxide-1,3-dioxolo4,5-e1,3,2dioxaphosphepin, 98%, (99% ee)
Brand Name
US-Strem
Product Number
15-8602
CAS
952649-50-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
15942421
IUPAC Name
(3aR,8aR)-6-hydroxy-2,2-dimethyl-4,4,8,8-tetranaphthalen-2-yl-3a,8a-dihydro-1,3dioxolo4,5-e1,3,2dioxaphosphepine 6-oxide
InChI Key
JDIGXFYRWGVNMW-NDOUMJCMSA-N
SMILES
CC1(OC@@H2C@@H(O1)C(OP(=O)(OC2(C3=CC4=CC=CC=C4C=C3)C5=CC6=CC=CC=C6C=C5)O)(C7=CC8=CC=CC=C8C=C7)C9=CC1=CC=CC=C1C=C9)C

Application

Technical Notes:
1.Ligand for the Zn-catalyzed asymmetric s immons-Smith cyclopropanation of both functionalized and unfunctionalized olefins.
References: 1.Adv. Synth. Catal. 2006, 348, 2363.