(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%|15-0528|1258327-07-9

(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%

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Product Information

Product Name
(11aS)-3,7-Bis3,5-bis(trifluoromethyl)phenyl-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin, min. 98%
Brand Name
US-Strem
Product Number
15-0528
CAS
1258327-07-9
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1. Org anocatalytic asymmetric multicomponent reactions of aromatic aldehydes and anilines with ß -ketoesters: facile and atom-
economicalaccoss tochiral tetrahvdroovridinos 2.Pd(O)- catalyzed tandem deprotection/cyclization of tetrahydro -ß carbolines on allenes: application to the synthesis of indolo[2, 3-a]quinolizidines .
3.Enantios elective synthesis of benzazepinoindoles bearing trifluoromethylated quaternary stereocenters, catalyzed by chiral spirocyclic phos phoric acids.
References:
1. Chem Commun., 2013, 49, 1401. 2.Org. Lett., 2014, 16, 1924.
3.Chem Commun., 2014, 50, 7538.