3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(1R,2R)-2-(dimethylamino)cyclohexyl]amino]-3-cyclobutene-1,2-dione, 98%, (99% ee)

Name: 3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(1R,2R)-2-(dimethylamino)cyclohexyl]amino]-3-cyclobutene-1,2-dione, 98%, (99% ee) | 1211565-07-9
Brand: US-Strem
SKU: SC07-7129_100_MG
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Sku SC07-7129_100_MG

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Product Information

Product Name

3-3,5-Bis(trifluoromethyl)phenylamino-4-(1R,2R)-2-(dimethylamino)cyclohexylamino-3-cyclobutene-1,2-dione, 98%, (99% ee)

Brand Name

US-Strem

Product Number

07-7129

CAS

1211565-07-9

Certificate of Analysis (COA)

COA not found

General Information

PubChem CID

46201489

IUPAC Name

3-3,5-bis(trifluoromethyl)anilino-4-(1R,2R)-2-(dimethylamino)cyclohexylaminocyclobut-3-ene-1,2-dione

InChI Key

QQXCDABMANNFAA-ZIAGYGMSSA-N

SMILES

CN(C)C@@H1CCCCC@H1NC2=C(C(=O)C2=O)NC3=CC(=CC(=C3)C(F)(F)F)C(F)(F)F

Application

Technical Notes:
1.Neber Reaction: The first enantioselective Neber reaction of ß-ketoxime sulfonates catalyzed by a bifunctional thiourea has been developed.
References:
1.Org. Lett., 2011, 13, 6374-6377.

References

Asymmetric Synthesis of Spiro Tetrahydrothiophene-indan-1,3-diones via a Squaramide-Catalyzed Sulfa-Michael/Aldol Domino Reaction

Publication Name: Synthesis

Publication Date: 2016-02-15

DOI: 10.1055/s-0035-1560412

Michael Addition Initiated Substrate- or Catalyst-Controlled Chemodivergent Three-Component Construction of Fused and Bridged Polycyclic Heterocycles

Publication Name: Synthesis

Publication Date: 2015-03-11

DOI: 10.1055/s-0034-1380229

Organocatalytic Asymmetric Domino Michael/Henry Reaction of Indolin-3-ones with o-Formyl-β-nitrostyrenes

Publication Name: Synthesis

Publication Date: 2015-01-05

DOI: 10.1055/s-0034-1379943

(11aR)-3,7-Bis(4-chlorophenyl)-10,11,12,13-tetrahydro-10,10,13,13-tetramethyl-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, 98%

(1'R,2'R,3aS,3"aS,8aR,8"aR)-(+)-3,3",3a,3"a,8,8",8a,8"a-Octahydrodispiro{2H-indeno[1,2-d]oxazole-2,1'-cyclohexane-2',2"-[2H]indeno[1,2-d]oxazole} WOLF BISOXAZOLIDINE

(11aR)-3,7-Di-9-anthracenyl-10,11,12,13-tetrahydro-10,10,13,13-tetramethyl-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, 95%, (99% ee)

(3aS,8aS)-Tetrahydro-6-hydroxy-2,2-dimethyl-4,4,8,8-tetra-2-naphthalenyl-6-oxide-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin, 98%, (99% ee)

(3aR,8aR)-4,4,8,8-Tetrakis(3,5-di-tert-butylphenyl)-2,2-bis(4-fluorophenyl)-6-hydroxy-tetrahydro-6-oxide-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine, 98%, (99% ee)

(11aS)-3,7-Bis(4-nitrophenyl)-10,11,12,13-tetrahydro-10,10,13,13-tetramethyl-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, 95%, (99% ee)

Phenyl sulfonic acid ethyl sulfide Silica (PhosphonicS SPhSA)

(3aR,8aR)-4,4,8,8-Tetrakis(3,5-di-tert-butylphenyl)-6-hydroxy-2,2-bis(4-(trifluoromethyl)phenyl)tetrahydro-6-oxide-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine, 98%

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(1R,2R)-2-(dimethylamino)cyclohexyl]amino]-3-cyclobutene-1,2-dione, 98%, (99% ee)

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Product Information

General Information

Application

References

Asymmetric Synthesis of Spiro Tetrahydrothiophene-indan-1,3-diones via a Squaramide-Catalyzed Sulfa-Michael/Aldol Domino Reaction

Michael Addition Initiated Substrate- or Catalyst-Controlled Chemodivergent Three-Component Construction of Fused and Bridged Polycyclic Heterocycles

Organocatalytic Asymmetric Domino Michael/Henry Reaction of Indolin-3-ones with o-Formyl-β-nitrostyrenes

Efficient Construction of Chiral Spiro[benzo][g]chromene-oxindole