3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(9R)-10,11-dihydro-6'-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione, 98%, (99% ee)|07-7028|1407166-63-5

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(9R)-10,11-dihydro-6'-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione, 98%, (99% ee)

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Product Information

Product Name
3-3,5-Bis(trifluoromethyl)phenylamino-4-(9R)-10,11-dihydro-6'-methoxycinchonan-9-ylamino-3-cyclobutene-1,2-dione, 98%, (99% ee)
Brand Name
US-Strem
Product Number
07-7028
CAS
1407166-63-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
145864855
IUPAC Name
3-3,5-bis(trifluoromethyl)anilino-4-(R)-(2R,4S,5S)-5-ethyl-1-azabicyclo2.2.2octan-2-yl-(6-methoxyquinolin-4-yl)methylaminocyclobut-3-ene-1,2-dione
InChI Key
OFXKFCTYZMFMJB-OQGFRWRESA-N
SMILES
CCC@@H1CN2CCC@H1CC@@H2C@@H(C3=C4C=C(C=CC4=NC=C3)OC)NC5=C(C(=O)C5=O)NC6=CC(=CC(=C6)C(F)(F)F)C(F)(F)F

Application

Technical Notes:
1.Conjugate Addition: Conjugate addition reactions of a wide range of nucleophilic enol species with enones, catalyzed by a cinchona alkaloid derived thiourea orga nocatalyst, have been developed with attending good yields and high enantioselectivities under a mild reaction condition.
References:
1. J. Am. Chem. Soc., 2006, 128, 12652-1 2653.