(S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide, 95%, (98% ee)|07-1417|959979-30-7

(S)-2-[[3,5-Bis(trifluoromethyl)phenyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide, 95%, (98% ee)

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Sku SC07-1417_100_MG
US-Strem
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Product Information

Product Name
(S)-2-3,5-Bis(trifluoromethyl)phenylthioureido-N-benzyl-N,3,3-trimethylbutanamide, 95%, (98% ee)
Brand Name
US-Strem
Product Number
07-1417
CAS
959979-30-7
Certificate of Analysis (COA)​
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Application

Technical Notes:
1.aza-MichaeI Reaction - Catalyst for the formal addition of ammonia to nitroalkenes, affording optically active
ß-amino nitro compounds in high yields and enantioselectivities. The approach is based on a novel thiourea- catalyzed aza-MichaeI reaction, by which benzophenone imine serves as a masked ammonia equiv., which is released by hydrolysis.
2.Diels-Alder Reaction - A variety of organocatalysts were screened for the catalysis of the naphthoquinone monoketal Diels-Alder reaction.
References:
1.Chem.-Eur. J., 2010, 16, 13330-13334
2. Beilstein J. Org. Chem., 2013, 9, 1414-1418.