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Sku SC07-1170_100_MG
US-Strem
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Product Information

Product Name
(2R)-(-)-N-Methyl-α;,α;-diphenyl-2-pyrrolidinemethanol, min. 98%
Brand Name
US-Strem
Product Number
07-1170
CAS
144119-12-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
853010
IUPAC Name
(2R)-1-methylpyrrolidin-2-yl-diphenylmethanol
InChI Key
XIJAGFLYYNXCAB-QGZVFWFLSA-N
SMILES
CN1CCCC@@H1C(C2=CC=CC=C2)(C3=CC=CC=C3)O

Description

Technical Notes:
1.Microwave assisted aryl transfer to aldehydes using the ligand .
2.Ligand used in the synthesis of enantioenriched a-(hydroxyalkyl)-tri-n-butylstannanes.
3.Catalytic asymmetric arylation of aliphatic aldehydes using a B/Zn exchange reaction.
4.Oxy-allyl cation catalysis: An enantioselective electrophilic activation mode.
References:
1.J. Org. Chem., 2008, 73, 2879.
2.Angew. Chem. Int. Ed., 2008, 47, 6586.
3.Tetrahedron, 2015, 71, 1202.
4.J. Am. Chem. Soc., 2016, 138, 2134.

References Data Source From Pubchem

Mixed Organobismuth/Dialkylzinc Reagents for Aryl Transfers

Publication Name: Synfacts
Publication Date: 2007-07-24
DOI: 10.1055/s-2007-968728

Synthesis of (+)-Acutiphycin

Publication Name: Synfacts
Publication Date: 2007-04
DOI: 10.1055/s-2007-968281

Electrophilic Substitution of 2-Lithiopyrrolidine and 2-Lithiopiperidine (Scalemic)

Publication Name: Science of Synthesis
Publication Date: 2006