CAS # | 479423-21-7 |
SMILES | |
Chemical Purity | |
Molecular Formula | C21H34N4OS |
Chemical Formula | |
Formula Weight | 390.60 |
Reaction | |
Note |
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Sku SC07-0956_50_MG
US-Strem
General Details
Physical Properties
Purity | 98%, (99% ee) |
Density | |
Melting Point | |
Boiling Point | |
Flash Point | |
Vapor Pressure | |
Surface Area | |
Pore Volume | |
Specific Rotation |
Shipping & Stability
Safety | Yes |
Store Cold | |
Dry Ice | |
Alternative Product for Air Shipment | |
Export Limitations | |
Pyrophoric | |
Hygroscopic | |
Air Sensitive | |
Light Sensitive | |
Heat Sensitive | |
Moisture Sensitive | |
Odorous Material |
Technical Notes:
1.Conjugate Addition: Primary amine -thiourea derivative is an active and highly enantioselective catalyst for the conjugate addition of ketones to nitroalkenes.
2.Michael Addition: The asymmetric Michael addition of dioxindoles to ß-substituted nitroalkenes is reported. The bifunctional primary amine-thiourea, by means of a non-covalent-based mode of catalysis, secures
direct access to 3-substituted 3-hydroxyoxindole derivatives with high stereocontrol.
References:
1. J. Am. Chem. Soc., 2006, 128, 7170-7171.
2. Chem. Commun., 2012, 48, 3336-3338.