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Sku SC15-5162_500_MG
US-Strem
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Product Information

Product Name
(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin-5-bis(R)-1-phenylethylamine, min. 98% (R)-SIPHOS-PE
Brand Name
US-Strem
Product Number
15-5162
CAS
500997-69-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11081701
IUPAC Name
N,N-bis(1R)-1-phenylethyl-4,5,6,7-tetrahydroiindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin-12-amine
InChI Key
ZXLQLIDJAURBDD-HRPAVAKOSA-N
SMILES
CC@H(C1=CC=CC=C1)N(C@H(C)C2=CC=CC=C2)P3OC4=CC=CC5=C4C6(CC5)CCC7=C6C(=CC=C7)O3

Application

Technical Notes:
1. Chiral ligands for coppe r-catalyzed asymmetric allylic alkylation with dialkylzincs .
2. Chiral ligands for copper-catalyzed asymmetric conjugate addition of diethylzinc to enones.
3. Chiral ligands for palladium- catalyzed asymmetric hydrosilylation of sty
4. Chiral ligands for copper catalyzed asymmetric ring-opening of oxabicyclic alkenes with Grignard re agents. 5. Chiral ligands for nickel-catalyzed asymmetric hydrovinylation of a-alkyI vinylarenes.
6. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic enamines.
7.Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic imines .
8. Chiral ligands for gold-catalyzed asymmetric 2 + 2 cycloaddition reaction.
9. Chiral ligands for rhodium-catalyzed asymmetric hydroacylation of salicylaldehydes to homoallylic sulfides. 10. Chiral ligands for palladium-catalyzed asymmetric carboamination reactions.

References Data Source From Pubchem

Catalytic Asymmetric Construction of CF3-Substituted Chiral sp3 Carbon Centers

Publication Name: Synthesis
Publication Date: 2022-06-09
DOI: 10.1055/a-1833-8813

Stereoselective Domino Reactions in the Synthesis of Spiro Compounds

Publication Name: Synthesis
Publication Date: 2022-05-16
DOI: 10.1055/a-1771-0641

Access to Oxazaborolidines by Catalytic Cycloaddition of 1,2-Azaborines and Vinyl Ethylene Carbonate

Publication Name: Synfacts
Publication Date: 2022-02-16
DOI: 10.1055/s-0041-1737854

Pd-Catalyzed Carboamination Reaction for the Synthesis of Cyclic Sulfamides

Publication Name: Synfacts
Publication Date: 2016-06-17
DOI: 10.1055/s-0035-1562312