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Sku SC15-5151_500_MG
US-Strem
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Product Information

Product Name
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin-5-dimethylamine, min. 98% (S)-SIPHOS
Brand Name
US-Strem
Product Number
15-5151
CAS
443965-10-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11438749
IUPAC Name
N,N-dimethyl-4,5,6,7-tetrahydroiindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin-12-amine
InChI Key
RIDZEECIONITMW-UHFFFAOYSA-N
SMILES
CN(C)P1OC2=CC=CC3=C2C4(CC3)CCC5=C4C(=CC=C5)O1

Application

Technical Notes:
1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of a-dehydroamino esters. 2.Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of ß-dehydroaminoesters. 4.Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
5.Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction
6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes .

References Data Source From Pubchem

State-of-the-Art Advances in Enantioselective Transition-Metal-Mediated Reactions of Silacyclobutanes

Publication Name: Synthesis
Publication Date: 2022-09-21
DOI: 10.1055/a-1929-4890

Borane Addition to Aryl- and Alkylalkynes in Water

Publication Name: Science of Synthesis
Publication Date: 2019

Asymmetric Copper-Catalyzed C(sp)–H Bond Insertion of Carbenoids Derived from N-Tosylhydrazones

Publication Name: Synlett
Publication Date: 2018-09-14
DOI: 10.1055/s-0037-1611003