(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine, min. 98%|15-1505|213843-90-4

(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine, min. 98%

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Product Information

Product Name
(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-1,3dioxolo4,5-e1,3,2dioxaphosphepin-6-yl)dimethylamine, min. 98%
Brand Name
US-Strem
Product Number
15-1505
CAS
213843-90-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11145951
IUPAC Name
(3aR,8aR)-N,N,2,2-tetramethyl-4,4,8,8-tetraphenyl-3a,8a-dihydro-1,3dioxolo4,5-e1,3,2dioxaphosphepin-6-amine
InChI Key
DRPNADVMTMEWQY-LOYHVIPDSA-N
SMILES
CC1(OC@@H2C@@H(O1)C(OP(OC2(C3=CC=CC=C3)C4=CC=CC=C4)N(C)C)(C5=CC=CC=C5)C6=CC=CC=C6)C

Application

Technical Notes:
1. Monodendate ligand for the enantioselective intramolecular reaction of prochiral cyclohexadienones .
2.Ligand use in the palladium-catalyzed, enantioselective diboration of allenes.
3.Enantioselective Rh-catalyzed2+2+2 cycloaddition of alkynes and isocyanates. 4.Palladium-catalyzed enantioselective C-H arylation.
5.Palladium-catalyzed dynamic kinetic cross-coupling
6.Palladium-catalyzed enantioselective C-H arylation.

References Data Source From Pubchem

Ring-Expansion Reactions Involving Allenes
Publication Name: Science of Synthesis
Publication Date: 2022

Cross Coupling
Publication Name: Science of Synthesis
Publication Date: 2022

Challenging Atroposelective C–H Arylation
Publication Name: SynOpen
Publication Date: 2020-10
DOI: 10.1055/s-0040-1705981

Palladium-Catalyzed Enantioselective Synthesis of 1H-Isoindoles
Publication Name: Synfacts
Publication Date: 2018-11-19
DOI: 10.1055/s-0037-16110103

Asymmetric Copper-Catalyzed C(sp)–H Bond Insertion of Carbenoids Derived from N-Tosylhydrazones
Publication Name: Synlett
Publication Date: 2018-09-14
DOI: 10.1055/s-0037-1611003