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Sku SC46-1781_1_G
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General Details
CAS # 3375-31-3
SMILES
Chemical Purity
Molecular Formula Pd(OOCCH3)2
Chemical Formula
Formula Weight 224.5
Reaction
Note
Physical Properties
Purity (99.95+%-Pd)
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1.Efficient catalyst for the arylation of olefins (Heck reaction).
2.Catalyst for cross -coupling reactions .
3.Catalyst for C-H activation.
4. Precatalyst for enantioselective decarboxylative protonation of allyl ß-ketoesters.
References:
1.Angew. Chem. Int. Ed., 1994, 33, 2379.
2.Acta. Chem. Scand., 1993, 47, 221 .
3.J. Org. Chem., 1994, 59, 5034.
4.Palladium Reagents in Organic Synthesis (R.F. Heck), 1985, Chapter 6.
5.Comprehensive Organic Synthesis, 1991, Vol. 3, Chapter 2.
6.Encyclopedia of Reagents for Organic Synthesis, 1995, Vol. 6, 3847.
7.Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., Wiley- Interscience, New York, 2002.
8.Org. L ett., 2008, 10, 3505.
9.J.Am. Chem. Soc., 2008, 130, 14090.
10. J. Am. Chem. Soc., 2006, 128, 11348.