(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%|26-0252|174467-31-3

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%

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Sku SC26-0252_100_MG
US-Strem
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Product Information

Product Name
(S,S)-(-)-2,2'-Bis(R)-(N,N-dimethylamino)(phenyl)methyl-1,1'-bis(diphenylphosphino)ferrocene, min. 97%
Brand Name
US-Strem
Product Number
26-0252
CAS
174467-31-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
91998450
IUPAC Name
bis(1-(2-diphenylphosphanylcyclopentyl)-N,N-dimethyl-1-phenylmethanamine);iron
InChI Key
XFBHAASESPONRW-UHFFFAOYSA-N
SMILES
CN(C)C(C1CCCC1P(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.CN(C)C(C1CCCC1P(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Fe

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes:
1.Ligand used for the palladium-catalyzed asymmetric coupling of potassium crotyltrifluoroborate with methyl 4-bromobenzoate. References:
1.Organometallics, 2009, 28, 152.
2.Chem. Eur. J.2009, 15, 13318.
3.Angew. Chem. Int. Ed. 2012, 51, 11510. 4.Org. Lett. 2014, 16, 1948.