(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene, min. 97%|26-0248|876608-69-4

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene, min. 97%

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Product Information

Product Name
(S,S)-(-)-2,2'-Bis(R)-(N,N-dimethylamino)(phenyl)methyl-1,1'-bisdi(3,5-dimethyl-4-methoxyphenyl)phosphinoferrocene, min. 97%
Brand Name
US-Strem
Product Number
26-0248
CAS
876608-69-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
145705918
IUPAC Name
bis(1-2-bis(4-methoxy-3,5-dimethylphenyl)phosphanylcyclopentyl-N,N-dimethyl-1-phenylmethanamine);iron
InChI Key
JLZZZSGLLNEMEF-UHFFFAOYSA-N
SMILES
CC1=CC(=CC(=C1OC)C)P(C2CCCC2C(C3=CC=CC=C3)N(C)C)C4=CC(=C(C(=C4)C)OC)C.CC1=CC(=CC(=C1OC)C)P(C2CCCC2C(C3=CC=CC=C3)N(C)C)C4=CC(=C(C(=C4)C)OC)C.Fe

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Note:
1. Ligand for the palladium-catalyzed asymmetric coupling of potassium crotyltrifluoroborate with
methyl 4-bromobenzoate
2.Ligand for the nickel-catalyzed , enantioselective, C-acylation of a-substituted lactams.
3.Ligand for Pd-catalyzed Enantioselective Conjunctive Cross-Coupling between Grignard-Derived Boron "Ate" Complexes and C(sp2) Halides or Triflates.
4.Ligand for Pd-catalyzed Asymmetric Conjunctive Cross-Coupling of Bis(alkenyl)borate Complexes.
References:
1.Organometallics, 2009, 28, 152.
2.J. Am. Chem. Soc., 2016, 138, 8997.
3.J. Am. Chem. Soc. 2017, 139, 3153-3160. 4.J. Am. Chem. Soc. 2017, 139, 5027-5030.