(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%|26-0244|494227-36-0

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%

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Product Information

Product Name
(S,S)-(-)-2,2'-Bis(R)-(N,N-dimethylamino)(phenyl)methyl-1,1'-bisdi(3,5-trifluoromethylphenyl)phosphinoferrocene, min. 97%
Brand Name
US-Strem
Product Number
26-0244
CAS
494227-36-0
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1.Ligand for Rh-catalyzed asymmetric hydrogenation of a-acetamidoacrylates.
2. Ligand for Rh-catalyzed hydrogenation of a- and ß- enamides, acrylic acid derivatives, itaconates, ß-ketoesters and 1 ,3diketones.
3.Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives .
4.Ligand for lr-catalyzed asymmetric transfer hydrogenation of ketones.
5.Ligand for Cu-catalyzed e nantiosele ctive hydroboration of a- and ß-unsaturated esters and nitriles.
References:
1. Chem. Eur. J., 1998, 4, 950.
2.Tetrahedron-Asymmetr., 1999, 10, 37 5.
3.Tetrahedron-Asymmetr., 2004, 15, 2299.
4.Chem. Eur. J., 2006, 12, 5376.
5.Chem. Eur. J., 2008, 14, 1 0388.
6.Angew. Chem. Int. Ed., 2008, 47, 145.