Product Name
Palladium(II) acetate, 99+% (99.95+%-Pd)
Certificate of Analysis (COA)
IUPAC Name
palladium(2+) diacetate
InChI Key
YJVFFLUZDVXJQI-UHFFFAOYSA-L
SMILES
CC(=O)O-.CC(=O)O-.Pd+2
Technical Notes:
1.Efficient catalyst for the arylation of olefins (Heck reaction).
2.Catalyst for cross -coupling reactions .
3.Catalyst for C-H activation.
4. Precatalyst for enantioselective decarboxylative protonation of allyl ß-ketoesters.
References:
1.Angew. Chem. Int. Ed., 1994, 33, 2379.
2.Acta. Chem. Scand., 1993, 47, 221 .
3.J. Org. Chem., 1994, 59, 5034.
4.Palladium Reagents in Organic Synthesis (R.F. Heck), 1985, Chapter 6.
5.Comprehensive Organic Synthesis, 1991, Vol. 3, Chapter 2.
6.Encyclopedia of Reagents for Organic Synthesis, 1995, Vol. 6, 3847.
7.Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., Wiley- Interscience, New York, 2002.
8.Org. L ett., 2008, 10, 3505.
9.J.Am. Chem. Soc., 2008, 130, 14090.
10. J. Am. Chem. Soc., 2006, 128, 11348.
Hawley - Lewis RJ. _Hawley's Condensed Chemical Dictionary, _15th Ed. New York: John Wiley & Sons, 2007.
L794: Wikipedia. Palladium. Last Updated 14 June 2009. http://en.wikipedia.org/wiki/Palladium
L798: International Programme on Chemical Safety (IPCS) INCHEM (2002). Environmental Health Criteria for Palladium. http://www.inchem.org/documents/ehc/ehc/ehc226.htm