Structure of SadPhos ligand showcasing its adaptive coordination with transition metals, highlighting its application in asymmetric synthesis

SadPhos ligand is a newly developed chiral ligand with adaptive coordination, created by the research group of Professor Zhang Junliang. This ligand features non-C2 symmetry and various coordination atoms with differing soft and hard properties. It can be used as a monophosphine ligand, or as an N,P-ligand, P,S-ligand, and P,O-ligand,...

By Vicky Zhao Read more
Scientific research results of Guo Zhiqian-Zhu Weihong research group | New high-performance quinolonitrile (QM) series fluorescent dyes

High-fidelity in vivo fluorescence monitoring of physiological processes is crucial in disease diagnosis and biological research, but it faces extreme challenges due to aggregation-induced quenching (ACQ) and short-wavelength fluorescence. The development of high-performance, long-wavelength aggregation-induced emission (AIE) fluorophores has placed higher demands on precise optical bioimaging.Chromophore-quinoline-malononitrile (quinolinenitrile, QM) is a...

By 向阳 翟 Read more
IMDN-Tf

  Vinylboronates and alkylboronates are key components in variegated transformations in all facets of chemical science. IMDN-Tf achieves fluoroalkylation-borylation in one step under mild reaction conditions. IMDN-Tf (Fig. 1), developed by Prof. Yi Pan of Nanjing University, is a trifluoromethylation reagent which can release trifluoromethyl radicals under photocatalytic conditions. In addition,...

By shuhan yang Read more
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