((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (R,R)-[COD]Ir[|77-5009|880262-14-6

((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (R,R)-[COD]Ir[

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Product Information

Product Name
((4R,5R)-(+)-O-1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (R,R)-CODIr
Brand Name
US-Strem
Product Number
77-5009
CAS
880262-14-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
73409324
IUPAC Name
cycloocta-1,5-diene;dicyclohexyl-2-(5-methyl-2-phenyl-4,5-dihydro-1,3-oxazol-4-yl)-1,3-diphenylpropan-2-yloxyphosphane;iridium;tetrakis3,5-bis(trifluoromethyl)phenylboranuide
InChI Key
LADOFGASZSKWMF-UHFFFAOYSA-N
SMILES
B-(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)(C3=CC(=CC(=C3)C(F)(F)F)C(F)(F)F)C4=CC(=CC(=C4)C(F)(F)F)C(F)(F)F.CC1C(N=C(O1)C2=CC=CC=C2)C(CC3=CC=CC=C3)(CC4=CC=CC=C4)OP(C5CCCCC5)C6CCCCC6.C1CC=CCCC=C1.Ir

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Note:
1. New class of hydrogenation catalyst which can convert unfunctionalized styrenyl olefins into alkanes with excellent enantioselectivity.
2. Ligand for Ir-catalyzed Asymmetric Hydrogenation of 1-Silyl-1 -substituted Alkenes.
References:
1. Adv. Synth. Catal., 2002, 344, 40.
2. Acc. Chem. Res., 2007, 40, 1402.
3. Tetrahedron L ett. 2016, 57, 5666 5668.