((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (R,R)-[COD]Ir[Ph2P|77-5019|880262-16-8

((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (R,R)-[COD]Ir[Ph2P

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Product Information

Product Name
((4R,5R)-(+)-O-1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl (diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (R,R)-CODIrPh2P
Brand Name
US-Strem
Product Number
77-5019
CAS
880262-16-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71310730
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;iridium;2-(4R,5R)-5-methyl-2-phenyl-4,5-dihydro-1,3-oxazol-4-yl-1,3-diphenylpropan-2-yloxy-diphenylphosphane;tetrakis3,5-bis(trifluoromethyl)phenylboranuide
InChI Key
OYQSQQMXRUOJGB-XCHXSORBSA-N
SMILES
B-(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)(C3=CC(=CC(=C3)C(F)(F)F)C(F)(F)F)C4=CC(=CC(=C4)C(F)(F)F)C(F)(F)F.CC@H1OC(=NC@H1C(OP(C2=CC=CC=C2)C3=CC=CC=C3)(CC4=CC=CC=C4)CC5=CC=CC=C5)C6=CC=CC=C6.C1/C=C\CC/C=C\C1.Ir

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Note:
1. New class of hydrogenation catalyst which can convert unfunctionalized styrenyl olefins into alkanes with excellent enantioselectivity
References:
1.Adv. Synth. Catal., 2002, 344, 40. 2. Acc. Chem. Res., 2007.40, 1402.