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Chloro(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II), [t-BuXPhos Palladacycle Gen. 1]|46-0264|1142811-12-8

Chloro(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II), [t-BuXPhos Palladacycle Gen. 1]

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Sku SC46-0264_100_MG
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Product Information

Product Name
Chloro(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)2-(2-aminoethyl)phenyl palladium(II), t-BuXPhos Palladacycle Gen. 1
Brand Name
US-Strem
Product Number
46-0264
CAS
1142811-12-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71310817
IUPAC Name
chloropalladium(1+);ditert-butyl-2-2,4,6-tri(propan-2-yl)phenylphenylphosphane;2-phenylethanamine
InChI Key
GITFHTZGVMIBGS-UHFFFAOYSA-M
SMILES
CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C(C)(C)C)C(C)(C)C)C(C)C.C1=CC=C(C-=C1)CCN.ClPd+

Description

Technical Notes:
1.Catalyst for cross-coupling reactions of electron-deficient anilines with aryl chlorides .
2.Catalyst for rapid C-N bond-forming process at low catalyst loading.
3.Catalyst for C-N cross-coupling reactions, at or below room tempe rature .
4.Efficient Pd-catalyzed amination reactions for heterocycle functionization.
References:
1. J. Am. Chem. Soc.2008, 130, 6686. 2. Org. L ett., 2010, 12, 4442.

References Data Source From Pubchem

Metal-Promoted Cross-Coupling Reactions
Publication Name: Science of Synthesis
Publication Date: 2024