Product Name
racemic-2-Di-t-butylphosphino-1,1'-binaphthyl, 98% TrixiePhos
Certificate of Analysis (COA)
IUPAC Name
ditert-butyl-(1-naphthalen-1-ylnaphthalen-2-yl)phosphane
InChI Key
QGBQGMHXBSLYLZ-UHFFFAOYSA-N
SMILES
CC(C)(C)P(C1=C(C2=CC=CC=C2C=C1)C3=CC=CC4=CC=CC=C43)C(C)(C)C
Technical Notes:
1. Ligand for the Pd-catalyzed formation of oxygen heterocycles .
2.Ligand for the inte rmolecular Pd-catalyzed synthesis of aryl ethers.
3.Ligand for the intramolecular Pd-catalyzed synthesis of aryl ethers.
4Ligand for the synthesis of carbazoles by Pd-catalyzed double N-arylation reaction.
5.Ligand for the Pd-catalyzed cyanation of (hetero)arylchlorides.
6.Ligand for the Pd-catalyzed intramolecular synthesis of carbazoles via C-H functionalization.
References:
1.J. Am. Chem. Soc., 2000, 122, 12907.
2.J. Am. Chem. Soc., 2001 , 123, 10770.
3.J. Am. Chem. Soc., 2001, 123, 12202.
4.Tetrahedron, 2006, 62, 6792.
5.Org. L ett., 2007, 9, 1711.
6.J. Am. Chem. Soc., 2010, 132, 14048.
7.Chem. Sci 2011.2. 27-50
