Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 98%|44-0222|329735-87-7

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 98%

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Sku SC44-0222_250_MG
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Product Information

Product Name
Dichloro(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl(1R,2R)-(+)-1,2-diphenylethylenediamineruthenium(II), min. 98%
Brand Name
US-Strem
Product Number
44-0222
CAS
329735-87-7
Certificate of Analysis (COA)​
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Application

Technical Note:
1. The NOYORI catalysts are a ruthenium-based system containing a phosphine and 1 2-diamine ligand. The catalysts are used in the highly- efficient, enantio and diastereoselective hydrogenation of simple ketones, usually under the mild conditions of room temperature and 1-10 atm of hydrogen pressure.
References:
1.J.Org. Chem.. 1996.61.4872.
2. Angew. Chem. Int. Ed.. 2001. 40, 40 (review article). 3. J. Am. Chem. Soc.. 1998, 120, 13529.
4. Angew. Chem. Int. Ed.. 1999, 38, 495.