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Sku SC15-0477_250_MG
US-Strem
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Product Information

Product Name
(S)-(-)-2,2'-Bisdi(3,5-xylyl)phosphino-1,1'-binaphthyl, 98% (S)-(-)-XylBINAP
Brand Name
US-Strem
Product Number
15-0477
CAS
135139-00-3
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1.See 15-0150.
2.See 15-0476.
3.Ligand used in copper- catalyzed as ymmetric Mannich-type reactions of N- acylimino esters.
4.Ligand used in the enantios elective fluorination of oxindoles .
5.Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
6. L igand used in the as ymmetric reduction of ketone via ruth enium-catalyzed transfer hydrogenation. 7.Asymmetric hydroboration of uns aturated imines .
References:
1. J. Am. Chem. Soc., 2003, 125, 2507.
2.J. Am. ( hem. Soc., 2005, 127, 10164.
3.Tetrahedron, 2008, 64, 82 1.
4.J. Am. Chem. Soc., 2011, 133, 10696.
5.Org. L ett., 2013, 15, 4810.