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Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct, min. 97%|44-0211|212143-24-3

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct, min. 97%

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Sku SC44-0211_250_MG
US-Strem
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Product Information

Product Name
Dichloro(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamineruthenium(II) dichloromethane adduct, min. 97%
Brand Name
US-Strem
Product Number
44-0211
CAS
212143-24-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
15482192
IUPAC Name
(2S)-1,1-bis(4-methoxyphenyl)-3-methylbutane-1,2-diamine;dichlororuthenium;1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl-diphenylphosphane
InChI Key
ZVVRWLPQKLDJRW-OGLOXHGMSA-L
SMILES
CC(C)C@@H(C(C1=CC=C(C=C1)OC)(C2=CC=C(C=C2)OC)N)N.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.ClRuCl

Safety Information

Storage Condition
Store at 2-8℃

Description

Technical Note:
l. The NOYORI catalysts are a ruthenium-based system containing a phosphine and 1,2-diamine ligand. The catalysts are used n the highlyefficient, enantio and diastereoselective hydrogenation of simple ketones. usually under the mild conditions of room temperature and 1-10 atm of hydrogen pressure.
References:
References:
1. J. Org. Chem., 1996, 61.4872.
2.Angew. Chem. Int. Ed., 2001, 40, 40 (review article).
3.J. Ám. Chem. Soc.. 1998, 120, 13529.
4.Angew. Chem Int. Ed., 1999.38. 495.

References Data Source From Pubchem

Ruthenium-Promoted Hydrogenation of Ketones
Publication Name: Science of Synthesis
Publication Date: 2009