Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-H8-binap)]Cl|44-0095|944451-27-8

Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-H8-binap)]Cl

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Sku SC44-0095_250_MG
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Product Information

Product Name
Chloro(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl(p-cymene)ruthenium(II) chloride RuCl(p-cymene)((S)-H8-binap)Cl
Brand Name
US-Strem
Product Number
44-0095
CAS
944451-27-8
Certificate of Analysis (COA)​
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Application

Technical Notes:
1. Biaryl bisphosphine ligand. The He-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)
2.The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.
References:
1. J. Org. Chem.. 1996, 61, 5510.
2.Topics Organometal. Chem. 2004, 6, 63 (review).