Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%|44-0073|437767-65-2

Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%

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Sku SC44-0073_5_G
US-Strem
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Product Information

Product Name
Bis(tricyclohexylphosphine)(phenylthio)methyleneruthenium(II) dichloride, min. 97%
Brand Name
US-Strem
Product Number
44-0073
CAS
437767-65-2
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1. Metathesis catalyst, stable in air and can be used in aqueous media.
2.Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins.
3.Catalyst concentration 2-3 times lower than comparable phenyl and vinyl substituted rutheniumcarbenes.
4.Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times.
5.Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.
References:
1. J. Organomet. Chem., 2000, 606, 16.
2. "Ring Opening Metathesis Polymerization of Related Chemistry", NATO Science Series II,2002, 23.
3.Organometallics, 2003, 22, 586.