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Sku SC42-0535_10_PCS
US-Strem
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Product Information

Product Name
2,6-Bis(1-methylethyl)benzenaminato(2-)(1R)-3,3'-dibromo-2'-(1,1-dimethylethyl)dimethylsilyloxy-5,5',6,6',7,7',8,8'-octahydro1,1'-binaphthalen-2-olato-kO(2,5-dimethyl-1H-pyrrol-1-yl)(2-methy
Brand Name
US-Strem
Product Number
42-0535
CAS
1103220-99-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
167994703
IUPAC Name
3-bromo-1-3-bromo-2-tert-butyl(dimethyl)silyloxy-5,6,7,8-tetrahydronaphthalen-1-yl-5,6,7,8-tetrahydronaphthalen-2-ol;2,5-dimethylpyrrol-1-ide;2,6-di(propan-2-yl)phenylimino-(2-methyl-2-phenylpropylidene)molybdenum
InChI Key
MGOKZPKYNACBIL-UHFFFAOYSA-N
SMILES
CC1=CC=C(N-1)C.CC(C)C1=C(C(=CC=C1)C(C)C)N=Mo=CC(C)(C)C2=CC=CC=C2.CC(C)(C)Si(C)(C)OC1=C(C=C2CCCCC2=C1C3=C4CCCCC4=CC(=C3O)Br)Br

Safety Information

Storage Condition
Store at 2-8℃

Description

Technical Notes:
1.Catalyst used in Z-selective cross metathesis.
2.Catalyst used in enantio- or diastereo-selective ene-yne ring closing metathesis .
References:
1.Nature, 2008, 456, 933-937 .
2.J. Am. Chem. Soc., 2011, 133, 11512 ,
3.J. Am. Chem. Soc., 2009, 131, 10652.
4.Org. Process Res. & Dev., 2016, 20, 1 709.