(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct|22-0780|328123-04-2

(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct

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Product Information

Product Name
(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato1,2-bis(dimethoxy)ethanetitanium(IV) dichloride acetonitrile adduct
Brand Name
US-Strem
Product Number
22-0780
CAS
328123-04-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
72376380
IUPAC Name
acetonitrile;cyclohexa-1,3-dien-1-yl-(4R,5R)-5-hydroxy(diphenyl)methyl-2,2-dimethyl-1,3-dioxolan-4-yl-phenylmethanol;dichlorotitanium;1,2-dimethoxyethane
InChI Key
YTJMLZYQYKUFOH-IWLCBTADSA-L
SMILES
CC#N.CC1(OC@H(C@@H(O1)C(C2=CC=CC=C2)(C3=CC=CC=C3)O)C(C4=CC=CCC4)(C5=CC=CC=C5)O)C.COCCOC.ClTiCl

Application

Technical Notes:
1.Catalyst used in the enantioselective fluorination of ß-ketoesters
2. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others. See reference (2).
References:
1. Angew. Chem. Int. Ed., 2000. 39, 4359
2. Angew. Chem. Int. Ed., 2001, 40, 92-138. (review article)