(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct|22-0761|197389-47-2

(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct

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Product Information

Product Name
(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
Brand Name
US-Strem
Product Number
22-0761
CAS
197389-47-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
72376378
IUPAC Name
acetonitrile;dichlorotitanium;(4R,5R)-5-hydroxy(dinaphthalen-1-yl)methyl-2,2-dimethyl-1,3-oxazolidin-4-yl-dinaphthalen-1-ylmethanol
InChI Key
WINAMCRSRUMNBX-VCYTWFGNSA-L
SMILES
CC#N.CC1(NC@H(C@@H(O1)C(C2=CC=CC3=CC=CC=C32)(C4=CC=CC5=CC=CC=C54)O)C(C6=CC=CC7=CC=CC=C76)(C8=CC=CC9=CC=CC=C98)O)C.ClTiCl

Application

Technical Notes:
1.Catalyst used in the enantioselective fluorination of ß-ketoesters.
2. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others. See refe rence (2).
References:
1.Angew. Chem. Int. Ed.. 2000, 39, 4359
2. Angew. Chem. Int. Ed., 2001, 40, 92-138. (review article)