(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct|22-0761|197389-47-2

(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct

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Product Information

Product Name
(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
Brand Name
US-Strem
Product Number
22-0761
CAS
197389-47-2
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1.Catalyst used in the enantioselective fluorination of ß-ketoesters.
2. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others. See refe rence (2).
References:
1.Angew. Chem. Int. Ed.. 2000, 39, 4359
2. Angew. Chem. Int. Ed., 2001, 40, 92-138. (review article)