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[S(R)]-N-[(1S)-2-(Diphenylphosphino)-1-[2-(diphenylphosphino)phenyl]ethyl]-2-methyl-2-propanesulfinamide, 95%|15-8392|1824731-39-6

[S(R)]-N-[(1S)-2-(Diphenylphosphino)-1-[2-(diphenylphosphino)phenyl]ethyl]-2-methyl-2-propanesulfinamide, 95%

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Sku SC15-8392_50_MG
US-Strem
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Product Information

Product Name
S(R)-N-(1S)-2-(Diphenylphosphino)-1-2-(diphenylphosphino)phenylethyl-2-methyl-2-propanesulfinamide, 95%
Brand Name
US-Strem
Product Number
15-8392
CAS
1824731-39-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
155293910
IUPAC Name
(R)-N-(1S)-2-diphenylphosphanyl-1-(2-diphenylphosphanylphenyl)ethyl-2-methylpropane-2-sulfinamide
InChI Key
ICLDONXQGZEXEU-CZNWIGJESA-N
SMILES
CC(C)(C)S@@(=O)NC@H(CP(C1=CC=CC=C1)C2=CC=CC=C2)C3=CC=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5

Description

Technical Notes:
1.Chiral sulfinamide bis phosphine ca talysts for highly enantioselective intermolecular cross -Rauhut-Currierreactions.
2.Used in phosphine-catalyzed asymmetric intermolecular cross-vinylogous Rauhut-Currier Reactions of vinyl Ketones with para-quinone methides .
3.Used in the enantioselective phosphine-catalyzed allylic alkylations of mix-indene with MBH carbonates .
4.Ligand for the Pd-catalyzed fast and living polymerizations of various diazoacetate monomers under mildconditions. 5.Ligand for the direct Pd-catalyzed cross-coupling reaction of easily accessible secondary phosphine oxides and aryl bromides, which provides rapid access to P-chiral phosphine oxides.