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[S(R)]-N-[(1S)-1-[2-(Diphenylphosphino)phenyl]-2,2-dimethylpropyl]-2-methyl-2-propanesulfinamide, 95%|15-8328|1595319-94-0

[S(R)]-N-[(1S)-1-[2-(Diphenylphosphino)phenyl]-2,2-dimethylpropyl]-2-methyl-2-propanesulfinamide, 95%

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Sku SC15-8328_100_MG
US-Strem
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Product Information

Product Name
S(R)-N-(1S)-1-2-(Diphenylphosphino)phenyl-2,2-dimethylpropyl-2-methyl-2-propanesulfinamide, 95%
Brand Name
US-Strem
Product Number
15-8328
CAS
1595319-94-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
155293901
IUPAC Name
(R)-N-(1S)-1-(2-diphenylphosphanylphenyl)-2,2-dimethylpropyl-2-methylpropane-2-sulfinamide
InChI Key
OMJJGAYXCQDARO-OOWIMERYSA-N
SMILES
CC(C)(C)C@@H(C1=CC=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3)NS@(=O)C(C)(C)C

Description

Technical Notes:
1.Ligand used for diastereo- and enantioselective Cu(I)- catalyzed intermolecular 3 +2 cycloaddition of
azomethine ylides with ß-trifluoromethyl ß,ß-Disubstituted enones.
2.Ligand used in the Copper(I)-catalyzed asymmetric intermolecular 3+2 cycloaddition of azomethine ylides with a-Trifluoromethyl a, ß-unsaturated esters .
3.Ligand used for Ag(l)-catalyzed enantioselective 3+2 cycloaddition of azomethine ylides .
References:
1.Angew. Chem. Int. Ed. 2016, 55, 6324.
2.ACS Catal. 2017, 7, 210.
3.Org. Biomol. Chem., 2019, 17, 1395.