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Product Information

Product Name
Trihexyl(tetradecyl)phosphonium chloride, min. 95% CYPHOS IL 101
Brand Name
US-Strem
Product Number
15-6382
CAS
258864-54-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11375816
IUPAC Name
trihexyl(tetradecyl)phosphanium chloride
InChI Key
JCQGIZYNVAZYOH-UHFFFAOYSA-M
SMILES
CCCCCCCCCCCCCCP+(CCCCCC)(CCCCCC)CCCCCC.Cl-

Application

Product Introduction

Trihexyl(tetradecyl)phosphonium chloride (CAS No. 258864-54-9) is a hydrophobic phosphonium-based ionic liquid widely used in catalysis, extraction chemistry, electrochemistry, separation science, and advanced materials research. Owing to its excellent thermal stability, negligible vapor pressure, broad liquid temperature range, and outstanding chemical stability, it has become one of the most widely studied phosphonium ionic liquids in both academic and industrial research.

This ionic liquid is frequently employed as a phase-transfer medium, extraction solvent, catalyst support, electrolyte component, and functional solvent. It is also used in the preparation of ionic liquid-based polymer composites, nanomaterials, and electrochemical devices.

Chemical Properties

Chemical Information

  • Chemical Name: Trihexyl(tetradecyl)phosphonium Chloride
  • Synonyms: Tetradecyl(trihexyl)phosphonium Chloride; CYPHOS® IL 101
  • CAS Number: 258864-54-9
  • Molecular Formula: C₃₂H₆₈ClP
  • Molecular Weight: 519.32
  • Appearance: Colorless to light yellow clear liquid
  • Purity: Typically ≥97%
  • Physical State: Ionic liquid 

Chemical Characteristics

This phosphonium ionic liquid offers:

  • High thermal stability
  • Low volatility
  • Excellent ionic conductivity
  • Good chemical stability
  • Strong hydrophobicity
  • Wide electrochemical window
  • Good compatibility with a variety of organic solvents and polymers

Trihexyltetradecylphosphonium chloride is widely utilized in research focused on:

Biological Applications: This compound serves as a phosphonium salt, which can enhance the solubility of various biomolecules, making it useful in drug formulation and delivery systems.

Surface Modification: It is employed in modifying surfaces of nanoparticles and other materials, improving their stability and functionality in applications such as catalysis and sensors.

Electrochemistry: The compound is valuable in electrochemical studies, particularly in the development of ionic liquids, which can improve the efficiency of batteries and supercapacitors.

Emulsification: It acts as an effective emulsifier in the food and cosmetic industries, helping to stabilize oil-water mixtures and enhance product texture.

Environmental Applications: Trihexyltetradecylphosphonium chloride is used in the extraction of heavy metals from wastewater, providing a method for pollution control and resource recovery.

Recommended Experimental Conditions

Parameter Recommended Conditions
Storage Temperature Room temperature (cool, dry place)
Atmosphere Store under inert gas for long-term storage
Moisture Protection Recommended (hygroscopic)
Common Solvents Methanol, dichloromethane, chloroform and other compatible organic solvents
Handling Avoid prolonged exposure to moisture

Advantages

  • Excellent thermal and chemical stability
  • Negligible vapor pressure
  • High ionic conductivity
  • Wide liquid-phase temperature range
  • Suitable for catalyst recycling
  • Excellent extraction performance
  • Ideal for ionic liquid and electrochemical research
  • Compatible with various advanced material systems

FAQ

Frequently Asked Questions (FAQ)

 

What is Trihexyl(tetradecyl)phosphonium chloride used for?
It is primarily used as a phosphonium ionic liquid for catalysis, extraction processes, electrochemistry, separation science, and advanced materials research.

 

Why are phosphonium ionic liquids attractive for research?
Compared with many conventional solvents, phosphonium ionic liquids generally exhibit high thermal stability, low volatility, excellent chemical stability, and broad electrochemical windows, making them suitable for demanding research applications.

 

Can this ionic liquid be used as a reaction medium?
Yes. It is commonly employed as a functional solvent or reaction medium for catalytic reactions, biphasic systems, and green chemistry studies.

 

Is this compound suitable for electrochemical applications?
Yes. It is widely investigated as an electrolyte component in electrochemical devices, energy storage systems, and sensor development.

 

Can it be used in extraction and separation research?
Yes. Researchers frequently use it in metal ion extraction, solvent extraction, and liquid–liquid separation studies.

 

Is this ionic liquid compatible with polymer materials?
Yes. It is commonly incorporated into polymer electrolytes, ionic gels, membranes, and composite materials to improve ionic conductivity and material performance.

 

How should this product be stored?
Store it in a tightly sealed container in a cool, dry place. Because it is hygroscopic, minimizing exposure to moisture and storing under an inert atmosphere for long-term preservation is recommended.

 

Is this product intended for research use only?
Yes. This product is intended for laboratory research and development only and is not intended for pharmaceutical, food, or household applications.

References

Trihexyltetradecylphosphonium chloride based ratiometric fluorescent nanosensors for multiplex anion discrimination

Publication Name: The Analyst
Publication Date: 2022-07-12
DOI: 10.1039/d2an00735e

Direct Synthesis from Difluorotris(perfluoroethyl)phosphorane

Publication Name: Science of Synthesis
Publication Date: 2022

Rh(III) Aqueous Speciation with Chloride as a Driver for Its Extraction by Phosphonium Based Ionic Liquids

Publication Name: Molecules (Basel, Switzerland)
Publication Date: 2019-04-09
DOI: 10.3390/molecules24071391

Characterization of a Novel Intrinsic Luminescent Room‐Temperature Ionic Liquid Based on [P6,6,6,14][ANS]

Publication Name: Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Date: 2014-08-14
DOI: 10.1002/chem.201402534