1,2-Bis(dichlorophosphino)-1,2-dimethylhydrazine, min. 98%|15-0076|37170-64-2

1,2-Bis(dichlorophosphino)-1,2-dimethylhydrazine, min. 98%

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Sku SC15-0076_2_G
US-Strem
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Product Information

Product Name
1,2-Bis(dichlorophosphino)-1,2-dimethylhydrazine, min. 98%
Brand Name
US-Strem
Product Number
15-0076
CAS
37170-64-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
4361791
IUPAC Name
1,2-bis(dichlorophosphanyl)-1,2-dimethylhydrazine
InChI Key
QUBGOLWADXVEJJ-UHFFFAOYSA-N
SMILES
CN(N(C)P(Cl)Cl)P(Cl)Cl

Application

Technical Notes:
1.Nucleophilic substitution reactions on 15-0076 are sO versatile that careful control of the basicity and steric effects of the phosphorus centers are achievable by systematic tuning of the substituents.
2.The reaction of bis(hydrazido)phosphines with transition metal/organometallic precursors have generated a wide spectrum of coordination compounds. Mononuclear chelates of w(O), Mo(O), Pt(I) and Pd(l) can be prepared.
3.The N-N bond demonstrates remarkable thermal and hydrolytic stability.
References:
1. Inorg. Chem.1994, 33, 2695. 2.Chem. Ber.. 1994.127. 1335.
3.Inorg. Chem., 1995, 34, 5483.

References Data Source From Pubchem

Reaction of bis(dimethoxyphosphino)dimethylhydrazine (dmpdmh) with PhCCo3(CO)9: synthesis and X-ray characterization of the dmpdmh-bridged polymorphs of PhCCo3(CO)7[(MeO)2PN(Me)N(Me)P(OMe)2]
Publication Name: Journal of Chemical Crystallography
Publication Date: 1998-05
DOI: 10.1023/a:1022420410672