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2-Diphenylphosphino-2'-(N,N-dimethyl­amino))-1,1'-biphenyl, 98% PhDavePhos|15-1745|240417-00-9

2-Diphenylphosphino-2'-(N,N-dimethyl­amino))-1,1'-biphenyl, 98% PhDavePhos

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Sku SC15-1745_2_G
US-Strem
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Product Information

Product Name
2-Diphenylphosphino-2'-(N,N-dimethyl­amino))-1,1'-biphenyl, 98% PhDavePhos
Brand Name
US-Strem
Product Number
15-1745
CAS
240417-00-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2734939
IUPAC Name
2-(2-diphenylphosphanylphenyl)-N,N-dimethylaniline
InChI Key
JGFXUYLYPITYGR-UHFFFAOYSA-N
SMILES
CN(C)C1=CC=CC=C1C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4

Description

Technical Notes:
1.Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of arylbromides.
2.Ligand used for the Cu-catalyzed phos phorylation of alcohols .
3.Ligand for Pd-catalyzed C-H benzylation.
4. Ligand for palladium-catalyzed 4 + 2 benzannulation reaction.
References:
1.Org. L ett., 2005, 7, 3271. 2.Org. L ett, 2009, 1 1, 4160. 3.Org. L ett., 2013, 15, 2562.
4.Chem Sci 2011.2.27.

References Data Source From Pubchem

Synthesis of (+)-Cochlearol B
Publication Name: Synfacts
Publication Date: 2022-06-15
DOI: 10.1055/s-0041-1738541

Carbonyl Transposition Simplifies Synthesis
Publication Name: Synfacts
Publication Date: 2022-01-18
DOI: 10.1055/s-0041-1737248

Asymmetric C–H Functionalization Enabled by Pd/Chiral Phosphoric Acid Combined Catalysis
Publication Name: Synthesis
Publication Date: 2021-11-22
DOI: 10.1055/a-1662-7096

Regioselective Synthesis of Tetrasubstituted Olefins via an Alkenyl Catellani Reaction
Publication Name: Synfacts
Publication Date: 2020-01-21
DOI: 10.1055/s-0039-1691607

Palladium-Catalyzed C–H Arylation
Publication Name: Synfacts
Publication Date: 2018-06-18
DOI: 10.1055/s-0037-1610096