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Sku SC15-1145_50_G
US-Strem
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Product Information

Product Name
2-(Dicyclohexylphosphino)-2'-(N,N-di­methylamino))-1,1'-biphenyl, 98% DavePhos
Brand Name
US-Strem
Product Number
15-1145
CAS
213697-53-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2734217
IUPAC Name
2-(2-dicyclohexylphosphanylphenyl)-N,N-dimethylaniline
InChI Key
ZEMZPXWZVTUONV-UHFFFAOYSA-N
SMILES
CN(C)C1=CC=CC=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4

Description

Technical Notes:
1. Ligand used in the Pd-catalyzed Suzuki coupling and animation of unactivated aryl chlorides. T he reactions generally occur at room temperature and give high yields of product.
2. Ligand used in Pd-catalyzed C-N bond formation. A general synthesis of N6-aryl-2'-deoxyad enosine analogues.
3. Ligand used in Pd-catalyzed N-arylation of indoles .
4. Ligand used in Pd-catalyzed synthesis of aryl-tert-butyl ethers .
5.Effective ligand in the Pd-catalyzed arylation of ester enolates .
6.Ligand employed in arylation of ketone enolates using ortho-halo nitrobenezenes .
7. Ligand employed in the amination of aryl nonaflates using Pd catalysts.
8. Ligand used for cascade alkenyl amination/Heck reaction for the synthesis of indoles .
9. Ligand used in Pd-catalyzed Kumada-Corriu cross coupling at low temperatures.
10.Ligand used in Rh-catalyzed intramolecular hydroamination of unactivated terminal and internal
alkenes with primary and s econdary amines .
11. Ligand used in Au-catalyzed cyclois omerization of allenes.

References Data Source From Pubchem

Structural Features of Cationic Palladium(II) Acetylacetonate Complexes with Dialkylbiarylphosphine Ligands

Publication Name: Journal of Structural Chemistry
Publication Date: 2025-05
DOI: 10.1134/s0022476625050191

Mechanochemical Synthesis of Linear Melanin-like Polymer with Tunable Physical Properties

Publication Name: Chinese Journal of Polymer Science
Publication Date: 2025-04-15
DOI: 10.1007/s10118-025-3325-7

Palladium-Catalyzed C(sp2)—C(sp2) Cross-Coupling Reactions

Publication Name: Science of Synthesis
Publication Date: 2024

Palladium-Catalyzed Cross-Coupling Reactions of Aryl and Alkenyl Trifluoromethanesulfonates

Publication Name: Science of Synthesis
Publication Date: 2024

Iron-Catalyzed Cross-Coupling Reactions of Alkenyl Iodides with Alkyllithium Reagents

Publication Name: Science of Synthesis
Publication Date: 2024