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N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos|15-1092|1237588-12-3

N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos

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Product Information

Product Name
N-2-(di-1-adamantylphosphino)phenylmorpholine, 98% Mor-DalPhos
Brand Name
US-Strem
Product Number
15-1092
CAS
1237588-12-3
Certificate of Analysis (COA)​
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Description

Technical Notes:
1. PN-ligandfor use inthe Pd-catalyzed cross-coupling of ammonia and hydrazine:Ref. (2) with adiverse rangeof sercalybinerea, anblaseaarye hor deswiiowcatalystloading andmiaconaitions.ket) withdlamines ina
2.P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
3.P-N-ligand for use in the Pd-catalyzed for mono -cx arylation of ketones employing aryl chlorides, bromides, iodides, mesylates(Ref.7)andtosvlates
References:
1.Angew. Chem. Int. Ed., 2010, 49, 4071 .
2.Angew. Chem. Int. Ed., 2010, 49, 8686. 3.J. Am. Chem. Soc., 2010, 132, 18026.
4.J. Am. Chem. Soc., 2011 , 133, 51 94.
5.J. Org. Chem., 2012, 77, 1056.
6.Eur. J. Org. Chem., 2012, 3972.
7. Angew. Chem. Int. Ed., 2013, 52, 7242.