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Sku SC15-0569_25_MG
US-Strem
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General Details
CAS #
SMILES
Chemical Purity
Molecular Formula C32H19F10O4P
Chemical Formula
Formula Weight 688.44
Reaction
Note
Physical Properties
Purity 95%, (99% ee)
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1.Chiral Brønsted acid catalysis for enantioselective Hosomi-Sakurai reaction of imines with allyltrimethylsilane .
2.Chiral Brønsted acid catalysis for stereoselective Mannich-type reactions of in situ generated C-alkynyl imines with ß-keto esters.
3.Chiral Brønsted acid catalysis for Mannich-type reaction of N-Boc-iminium intermediates, generated in situ from N-Boc- aminals.
References:
1. Org. Lett., 2011, 13, 2126.
2.Angew. Chem. Int. Ed. 2013, 52, 1 1509. 3.Tetrahedron, 2016, 72, 3687.