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Sku SC15-0571_25_MG
US-Strem
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Product Information

Product Name
(11aR)-3,7-Bis3,5-bis(tert-butyl)phenyl-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin, 98%
Brand Name
US-Strem
Product Number
15-0571
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1.Used in asymmetric N- -H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoricacids.
2.Used in the chiral spiro phosphoric-acid-catalyzed regioselective and enantioselective C7-F riedel-Crafts alkylation of 4-Aminoindoles with trifluoromethyl ketones.
References:
1. Angew. Chem. Int. Ed. 2011, 50, 1 1483. 2. Org. Lett. 2019, 21, 3538.