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Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH₂Me₂][{RuCl((R)-dm-segphos®)}₂(μ-Cl)₃]|44-0520|935449-46-0

Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH₂Me₂][{RuCl((R)-dm-segphos®)}₂(μ-Cl)₃]

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Sku SC44-0520_5_G
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Product Information

Product Name
Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bisdi(3,5-xylyl)phosphino-4,4'-bi-1,3-benzodioxole}diruthenate(II) NH₂Me₂{RuCl((R)-dm-segphos®)}₂(μ-Cl)₃
Brand Name
US-Strem
Product Number
44-0520
CAS
935449-46-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71310535
IUPAC Name
bis(4-5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl-1,3-benzodioxol-5-yl-bis(3,5-dimethylphenyl)phosphane);N-methylmethanamine;ruthenium;trichloronioruthenium(1-);chloride;hydrochloride
InChI Key
CABGTUSYWYURQC-UHFFFAOYSA-M
SMILES
CC1=CC(=CC(=C1)P(C2=C(C3=C(C=C2)OCO3)C4=C(C=CC5=C4OCO5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CC1=CC(=CC(=C1)P(C2=C(C3=C(C=C2)OCO3)C4=C(C=CC5=C4OCO5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CNC.Cl.Cl-.ClH+Ru-(ClH+)ClH+.Ru

Description

Technical Notes:
1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-S EGPHOS® ligand, as the ruthenium complex, gives superior
enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of a-substituted-ß-ketoesters. See 15-0066.
2.Ruthenium catalyzed enantioselective synthesis of ß amino acids by hydrogenation
3.Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. See 44-0098 for Ru catalyst.
References:
1. U.S. Pat. 7626034. 2. U.S. Pat 7462722.