Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-dm-segphos?)]Cl|44-0098|944451-30-3

Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-dm-segphos?)]Cl

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Product Information

Product Name
Chloro{(R)-(+)-5,5'-bisdi(3,5-xylyl)phosphino-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride RuCl(p-cymene)((R)-dm-segphos?)Cl
Brand Name
US-Strem
Product Number
44-0098
CAS
944451-30-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
59052747
IUPAC Name
4-5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl-1,3-benzodioxol-5-yl-bis(3,5-dimethylphenyl)phosphane;dichlororuthenium;1-methyl-4-propan-2-ylbenzene
InChI Key
LLNJPFQWQJQPEH-UHFFFAOYSA-L
SMILES
CC1=CC=C(C=C1)C(C)C.CC1=CC(=CC(=C1)P(C2=C(C3=C(C=C2)OCO3)C4=C(C=CC5=C4OCO5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.ClRuCl

Application

Technical Notes:
1. Ruthenium catalyst used for the asymmetric hydrogenation of B-ketoimides.
Reference:
1. J. Org. Chem., 2012, 77, 4732.