Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][(phenylthio)methylene]ruthenium(II) dichloride

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Sku SC44-7780_500_MG
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General Details
CAS # 1155422-69-7
SMILES
Chemical Purity
Molecular Formula RuCl2[C21H26N2][C7H6S][P(C6H11)3]
Chemical Formula
Formula Weight 881.04
Reaction
Note
Physical Properties
Purity
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
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Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1.Metathesis catalyst, stable in air and can be used in aqueous media .
2.Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins .
3.Catalyst concentration 2-3 times lower than com parable phenyI and vinyI substituted rutheniumcarbenes.
4.Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times. 5.Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.
References:
1.J. Org· Chem.. 2000, 606, 65.
2.“Ring Opening Metathesis Polymerization of Related Chemistry", NATO Science Series II, 2002, 23. 3. 3.Organometallics, 2003, 22, 586.