[1,3-Bis(2,4,6-trimethylphenylimidazolidin-2-ylidene)]-(2-i-propoxy-5-nitrobenzylidene)ruthenium(II) dichloride nitro-Grela|44-0758|502964-52-5

[1,3-Bis(2,4,6-trimethylphenylimidazolidin-2-ylidene)]-(2-i-propoxy-5-nitrobenzylidene)ruthenium(II) dichloride nitro-Grela

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Sku SC44-0758_500_MG
US-Strem
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Product Information

Product Name
1,3-Bis(2,4,6-trimethylphenylimidazolidin-2-ylidene)-(2-i-propoxy-5-nitrobenzylidene)ruthenium(II) dichloride nitro-Grela
Brand Name
US-Strem
Product Number
44-0758
CAS
502964-52-5
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1. This catalyst is used for an efficient synthesis of HCV Protease Inhibitor, BILN 206 1

The nitro- Grela catalyst is a stable olefin metathesis initiator active in various ring-closing, cross, and enyne metathesis reactions. Its efficiency has been proven in numerous total syntheses of natural and biologically active compounds, and in material science (see Ref.1-9)
References:
1. Org. L ett., 2008, 10, 1303.
2.Org. Process Res. Dev., 2009, 13, 250.
3.Org. L ett., 2013, 15, 1016.
4.Chem. Eur. J., 2013, 19, 11847.
5.Org. L ett., 2010, 12, 248.
6.Angew. Chem. Int. Ed.. 2008. 47, 6483. 7.Tetrahedron L ett, 2006, 47, 6351
8.J. Am. Chem. Soc., 2004, 126, 9318.
9.Angew. Chem. Int. Ed.. 2002. 41.4038.