(1Z,3Z)-1,3-Bis[[(4R)-4,5-dihydro-4-phenyl-2-oxazolyl]methylene]-2,3-dihydro-1H-isoindole, 95%

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Sku SC07-1065_100_MG

Vendor: US-Strem

Product Information

Product Name

(1Z,3Z)-1,3-Bis(4R)-4,5-dihydro-4-phenyl-2-oxazolylmethylene-2,3-dihydro-1H-isoindole, 95%

Brand Name

US-Strem

Product Number

07-1065

CAS

1429056-54-1

Certificate of Analysis (COA)

COA not found

General Information

PubChem CID

132549124

IUPAC Name

(4R)-4-phenyl-2-(Z)-(3Z)-3-(4R)-4-phenyl-4,5-dihydro-1,3-oxazol-2-ylmethylideneisoindol-1-ylidenemethyl-4,5-dihydro-1,3-oxazole

InChI Key

GBRKRIUSANJDJX-HQJCERPHSA-N

SMILES

C1OC(=NC@@H1C2=CC=CC=C2)/C=C/3\N/C(=C\C4=NC@@H(CO4)C5=CC=CC=C5)/C6=CC=CC=C36

Safety Information

Storage Condition

Store at 2-8℃

Application

Technical Notes:
1.L igand for the enantioselective Fe-catalyzed azidation of ß-ketoesters and oxindoles .
2.Ligand for the enantioselective Fe-catalyzed hydrosilylation of ketones .
3.Ligand for the enantioselective Zn-catalyzed allylation of oxindole derivatives with allyl bromide. 4.Ligand for the Zn-catalyzed asymmetric electrophilic cyanation of 3-substituted oxindoles .
5.Ligand for the a-selective Co-catalyzed hydroborations of alkynes .

References

Enantioselective Cyanation of Oxindoles

Publication Name: Synfacts

Publication Date: 2017-10-19

DOI: 10.1055/s-0036-1591389