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Sku SC45-0195_2_G
US-Strem
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Product Information

Product Name
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
Brand Name
US-Strem
Product Number
45-0195
CAS
12354-85-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71310421
IUPAC Name
bis(dichlororhodium(1+));bis(1,2,3,4,5-pentamethylcyclopenta-1,3-diene)
InChI Key
AUBQNRPCZLEJIZ-UHFFFAOYSA-J
SMILES
CC-1C(=C(C(=C1C)C)C)C.CC-1C(=C(C(=C1C)C)C)C.ClRh+Cl.ClRh+Cl

Application

Technical Notes:
1.Catalyst used in the functionalization of acetanilides under s olventless conditions in a ball mill.
2.Rhodium- catalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
3.Catalyst used in the asymmetric transfer hydrogenation of imines in water.
4.Facile rhodium-catalyzed synthesis of fluorinated pyridines .
5.Rhodium-catalyzed alkylation of azobenzenes with allyl acetates .