Product Name
Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%
Certificate of Analysis (COA)
IUPAC Name
bis(iridium(3+));bis(1,2,3,4,5-pentamethylcyclopenta-1,3-diene);tetrachloride
InChI Key
MMAGMBCAIFVRGJ-UHFFFAOYSA-J
SMILES
CC-1C(=C(C(=C1C)C)C)C.CC-1C(=C(C(=C1C)C)C)C.Cl-.Cl-.Cl-.Cl-.Ir+3.Ir+3
Technical Notes:
1. Iridium-catalyzed c-3 alkylation of oxindole with alcohols.
2.Precursor to N-heterocyclic carbene catalyst effective for hydrogenation and alkylation of amines and alcohols. . 3.Precursor to efficient phosphine free catalyst for e nantioselective hydrogenation of quinoline derivatives.
4. Catalyst for oxidative c H activation
5. Precursor to an effective water oxidation catalyst.
References:
1.Tetrahedron, 2009, 65, 4375.
2.Organometallics, 2009, 321.
3. Org Lett.. 2008, 5265.
4. J. Am. Chem. Soc.. 2010, 132, 12550.
5. Organometallics, 2011, 30, 965.
