Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]|46-0335|2009020-38-4

Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]

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Product Information

Product Name
Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% RockPhos Palladacycle Gen. 3
Brand Name
US-Strem
Product Number
46-0335
CAS
2009020-38-4
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1.Palladium precatalyst used for the arylation of an aliphatic alcohol.
2.Palladium precatalyst used for the synthesis of diaryl ethers under mild conditions.
3.Palladium precatalyst used for the intermolecular C-0 bond formation with secondary and primaryalcohols.
References:
1.Org. L ett., 2013, 15, 2876.
2.Org. Lett., 2012, 14, 1 70.
3.Angew. Chem. Int. Ed., 2011, 50, 9943.