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Sku SC15-1152_1_G
US-Strem
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Product Information

Product Name
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Brand Name
US-Strem
Product Number
15-1152
CAS
1070663-78-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
25112535
IUPAC Name
dicyclohexyl-3,6-dimethoxy-2-2,4,6-tri(propan-2-yl)phenylphenylphosphane
InChI Key
WDVGNXKCFBOKDF-UHFFFAOYSA-N
SMILES
CC(C)C1=CC(=C(C(=C1)C(C)C)C2=C(C=CC(=C2P(C3CCCCC3)C4CCCCC4)OC)OC)C(C)C

Description

Technical Notes:
1.Versatile L igand for the Pd-c atalyzed coupling of primary arylamines and alkylamines .
a.See also 46-0367, 46-0267
b.See references 7,8
2.Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines . 3.Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading
4.Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
5.Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
6.Ligand for the palladium-c atalyzed trifluoromethylation of aryl chlorides .
7.Ligand for the palladium- catalyzed formation of aryl-SCFa compounds from aryl bromides .
8.Ligand for the nickel-catalyzed cross - coupling of styrenyl epoxides with boronic acids.
9.Ligand for the palladium catalyzed intramolecular CH difluoroalkylation.

References Data Source From Pubchem

Cyclolignan synthesis streamlined by enantioselective hydrogenation of tetrasubstituted olefins

Publication Name: Nature Synthesis
Publication Date: 2024-06-20
DOI: 10.1038/s44160-024-00564-y

Carbonylation of Aryl and Alkyl Halides, Arylboronic Acids, or Arenediazonium Salts

Publication Name: Science of Synthesis
Publication Date: 2024

Cross Coupling of Aryl Halides and Trifluoromethanethiolate Nucleophiles

Publication Name: Science of Synthesis
Publication Date: 2024

Predicting synthetic viability

Publication Name: Nature Synthesis
Publication Date: 2023-04-11
DOI: 10.1038/s44160-023-00297-4

A neural network model informs the total synthesis of clovane sesquiterpenoids

Publication Name: Nature Synthesis
Publication Date: 2023-03-20
DOI: 10.1038/s44160-023-00271-0