2-Dicyclohexylphosphino-2'-methyl-)-1,1'-biphenyl, min. 98% MePhos|15-1148|251320-86-2

2-Dicyclohexylphosphino-2'-methyl-)-1,1'-biphenyl, min. 98% MePhos

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US-Strem
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Product Information

Product Name
2-Dicyclohexylphosphino-2'-methyl-)-1,1'-biphenyl, min. 98% MePhos
Brand Name
US-Strem
Product Number
15-1148
CAS
251320-86-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2734938
IUPAC Name
dicyclohexyl-2-(2-methylphenyl)phenylphosphane
InChI Key
GPVWUKXZFDHGMZ-UHFFFAOYSA-N
SMILES
CC1=CC=CC=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4

Application

Technical Notes:
1. Ligand used for the Pd-catalyzed formation of a- arylketones
2.Ligand used for the Pd-catalyzed amination reaction (see 15- 1045)
a. See (Ref. 5).
3.Ligand used for the Pd-catalyzed hydrazone arylation.
4.Ligand used for the Pd-catalyzed synthesis of 5,5- disubstituted butenolides. 5.Ligand used for the Pd-catlyzed direct arylation of polyfluorinated arenes at room temperature .
References:
1.J. Am. Chem. Soc., 2000, 122, 1360. 2.Adv. Synth. Catal., 2007, 347, 773. 3.Org. L ett., 2009, 1 1, 2663
4.Org. Lett., 2010, 12, 2116.
5.Chem Sci. 2011 2.27.

References Data Source From Pubchem

Structural Features of Cationic Palladium(II) Acetylacetonate Complexes with Dialkylbiarylphosphine Ligands
Publication Name: Journal of Structural Chemistry
Publication Date: 2025-05
DOI: 10.1134/s0022476625050191

Palladium-Catalyzed Site-Selective Arylation of α,β-Unsaturated Carbonyl Compounds through a Ligand-Controlled Strategy
Publication Name: Synlett
Publication Date: 2022-02-01
DOI: 10.1055/s-0040-1719877

How Rhodium(I)-Catalyzed Phosphorus(III)-Directed C–H Bond Functionalizations Can Improve the Catalytic Activities of Phosphines
Publication Name: Synlett
Publication Date: 2022-01-10
DOI: 10.1055/s-0041-1737325

An Expedient Approach to Pyrazolo[3,4-b]pyridine-3-carboxamides via Palladium-Catalyzed Aminocarbonylation
Publication Name: Synthesis
Publication Date: 2021-08-26
DOI: 10.1055/s-0037-1610783

An Efficient Palladium-Catalyzed α-Arylation of Acetone Below its Boiling Point
Publication Name: Synlett
Publication Date: 2020-07-09
DOI: 10.1055/s-0040-1707887