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Sku SC15-8520_10_MG
US-Strem
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Product Information

Product Name
(11bR)-2,6-Bis4-(9-anthracenyl)-2,6-bis(isopropyl)phenyl-4-hydroxy-4-oxide-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 95%, (99% ee)
Brand Name
US-Strem
Product Number
15-8520
CAS
1236191-19-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
24970652
IUPAC Name
10,16-bis4-anthracen-9-yl-2,6-di(propan-2-yl)phenyl-13-hydroxy-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
InChI Key
VQUYUHARRUOTBV-UHFFFAOYSA-N
SMILES
CC(C)C1=CC(=CC(=C1C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=C(C=C(C=C7C(C)C)C8=C9C=CC=CC9=CC1=CC=CC=C18)C(C)C)O)C(C)C)C1=C2C=CC=CC2=CC2=CC=CC=C21

Application

Technical Notes:
1.Organocatalyst for enantioselective Friedel-Crafts alkylation reaction of indoles with a,ß-unsaturated acylphosphonates.
2.Used in the L ewis base/chiral Brønsted acid catalyzed enantioselective bromocycloetherification.
3.Chiral phosphoric acid catalyst for the kinetic resolution of indolines based on a self-redox re action.
References:
1.Chem. Commun. 2010, 46, 4112. 2.Org. Lett..2012, 14, 256
3.Angew. Chem. int. Ed. 2016, 55, 3148.

References

Chiral Phosphoric Acid Catalyzed Self-Redox Reaction of Indolines

Publication Name: Synfacts
Publication Date: 2016-03-15
DOI: 10.1055/s-0035-1561841

Using a Chiral Phosphoric Acid Catalyst

Publication Name: Science of Synthesis
Publication Date: 2016

Organocatalytic Asymmetric Hydrophosphonylation/Mannich Reactions Using Thiourea, Cinchona and Brønsted Acid Catalysts

Publication Name: Synlett
Publication Date: 2012-04-23
DOI: 10.1055/s-0031-1290193

Direct Catalytic Asymmetric Synthesis of Cyclic Aminals from Aldehydes

Publication Name: Synfacts
Publication Date: 2009-01-22
DOI: 10.1055/s-0028-1087573