(11bR)-2,6-Bis[3,5-bis(1,1-dimethylethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%|15-0562|861909-39-9

(11bR)-2,6-Bis[3,5-bis(1,1-dimethylethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%

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Product Information

Product Name
(11bR)-2,6-Bis3,5-bis(1,1-dimethylethyl)phenyl-4-hydroxy-4-oxide-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 98%
Brand Name
US-Strem
Product Number
15-0562
CAS
861909-39-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
99770987
IUPAC Name
10,16-bis(3,5-ditert-butylphenyl)-13-hydroxy-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
InChI Key
GEIVXBCFEGGBDI-UHFFFAOYSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1)C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=CC(=CC(=C7)C(C)(C)C)C(C)(C)C)O)C(C)(C)C

Application

Technical Notes:
1.(In or Ga )/Ag/chiral phosphoric catalyst for asymmetric Hosomi-Sakurai reactions with N,O-aminals using allyl boronates.
References:
1.Angew. Chem. Int. Ed 2011, 50, 11121. 2.J. Àm. Chem. Soc. 2016, 138, 13119.