Product Name
(11bR)-4-Hydroxy-9,14-dinitro-2,6-bis2,4,6-tris(1-methylethyl)phenyl-4-oxide-Dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 98%
Certificate of Analysis (COA)
IUPAC Name
13-hydroxy-6,20-dinitro-10,16-bis2,4,6-tri(propan-2-yl)phenyl-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(23),2,4,6,8,10,15,17,19,21-decaene 13-oxide
InChI Key
OVLNZSKDTWNWTF-UHFFFAOYSA-N
SMILES
CC(C)C1=CC(=C(C(=C1)C(C)C)C2=C3C(=C4C=CC(=CC4=C2)N+(=O)O-)C5=C6C=CC(=CC6=CC(=C5OP(=O)(O3)O)C7=C(C=C(C=C7C(C)C)C(C)C)C(C)C)N+(=O)O-)C(C)C
Technical Notes:
1.Organocatalyst used for the kinetic resolution of secondary alcohols.
2.Catalyst used in the kinetic resolution of ß-amino alcohols via asymmetric substitutions at sp3-hybridized carbon atoms .
3.Brønsted acid catalyst used for asymmetric desymmetrization of o-symmetric acid anhydrides.
References:
1.Angew. Chem. Int. Ed. 2013, 52, 10227.
2.Angew. Chem. Int. Ed. 2016, 55, 13137 .
3.Tetrahedron L ett.2016, 57, 4098.
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